METAL-MEDIATED CONVERSION OF A 5-AMINOTHIATRIAZOLE INTO A 5-MERCAPTOTETRAZOLYL LIGAND BY REACTION WITH A SOLID METAL HYDROXIDE - SYNTHESIS AND CRYSTAL-STRUCTURE OF [CYCLO-NAPHTHYLN-BULLET-N=N-BULLET-N-RADICAL-ANIONC(RADICAL-ANIONS)]2BA-BULLET-3HMPA

被引：22

作者：

BANBURY, FA ^{[1
]}

DAVIDSON, MG ^{[1
]}

MARTIN, A ^{[1
]}

RAITHBY, PR ^{[1
]}

SNAITH, R ^{[1
]}

VERHOREVOORT, KL ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 16期

关键词：

D O I：

10.1039/c39920001152

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid Ba(OH)2 suspended in toluene containing HMPA [O=P(NMe2)3] reacts with the 5-aminothiatriazole, naphthylNH.C=N.N=N.S, to give the monomeric 5-mercaptotetrazolylbarium complex, [naphthylN.N=N.N-C (-S)]2Ba.3HMPA, 1; the isolation and structural characterisation of 1 sheds new light on the known alkali-promoted rearrangement of 5-amino-substituted thiatriazoles into 5-thio-substituted tetrazoles.

引用

页码：1152 / 1154

页数：3

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