THE 1ST CALCIUM-MERCURY COCOMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE

被引：12

作者：

DAVIDSON, MG ^{[1
]}

LLEWELLYN, SC ^{[1
]}

SOLERA, MIL ^{[1
]}

RAITHBY, PR ^{[1
]}

SNAITH, R ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A solution of (OxS)2Ca.2HMPA [OxS- = 2-mercaptobenzoxazolyl, activated C6H4O.(C-S)-N-; HMPA = O:P (NMe2)3] dissolves solid HgCl2 to give [(OxS)CaCl.2HMPA]2.(OxS)2Ca.(HgCl2)2, 1; in the solid state, the Cl atoms of intact HgCl2 molecules coordinate to Ca2+ ions (which retain links to the N atoms of OxS- ligands) and the S centres are thereby displaced from Ca2+ and capture the Hg.

引用

页码：573 / 575

页数：3

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