METALLOPORPHYRIN-CATALYZED OXIDATION OF ALKANES WITH MOLECULAR-OXYGEN IN THE PRESENCE OF ACETALDEHYDE

被引：89

作者：

MURAHASHI, SI

NAOTA, T

KOMIYA, N

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka, 560, Machikaneyama

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 44期

关键词：

D O I：

10.1016/0040-4039(95)01708-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aerobic oxidation of alkanes with acetaldehyde in the presence of metalloporphyrins gives the corresponding alcohols and ketones highly efficiently. Extremely high turnover numbers have been obtained for the oxidations of cyclohexane using cobalt, manganese, and ruthenium porphyrin catalysts bearing meso-pentafluorophenyl groups.

引用

页码：8059 / 8062

页数：4

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