SYNTHESIS AND REACTIVITY OF 1,1-DISODIO-2,3,4,5-TETRAPHENYL-1-SILACYCLOPENTADIENE

被引：122

作者：

JOO, WC ^{[1
]}

HONG, JH ^{[1
]}

CHOI, SB ^{[1
]}

SON, HE ^{[1
]}

KIM, CH ^{[1
]}

机构：

[1] YONSEI UNIV, DEPT CHEM, SEOUL 120749, SOUTH KOREA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 391卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)80153-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1-Disodio-2,3,4,5-tetraphenyl-1-silacyclopentadiene (II, 1,1-disodio-TPSCp) was obtained from the reaction of 1,1-dichloro-2,3,4,5-tetraphenyl-1-silacyclopentadiene (1,1-dichloro-TPSCp) with sodium. The reaction of II with MeI and XSiMe2Cl (X = H, Me, Cl) gave the corresponding 1,1-dimethyl-, and 1,1-bis(XSiMe2)-TPSCp's, respectively. In contrast, the reaction with Me3ECl (E = C, Sn) gave bis(1-Me3E-2,3,4,5-tetraphenyl-1-silacyclopentadienyl). © 1990.

引用

页码：27 / 36

页数：10

共 19 条

[1] Atwell W. H., 1969, ANGEW CHEM, V81, P485
[2] DIVALENT SILICON INTERMEDIATES
ATWELL, WH
WEYENBER.DR
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (07) : 469 - &
[3] NEW UNSATURATED HETEROCYCLIC SYSTEMS .1.
BRAYE, EH
CAPLIER, I
HUBEL, W
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (21) : 4406 - &
[4] BRUNET JC, 1969, B SOC CHIM FR, P3424
[5] SYNTHESIS AND REACTIONS OF SOME FUNCTIONALLY SUBSTITUTED SILA- AND GERMACYCLOPENTADIENES
CURTIS, MD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (22) : 6011 - &
[6] FUNCTIONALLY SUBSTITUTED SILA- AND GERMACYCLOPENTADIENES . ANION FORMATION
CURTIS, MD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (16) : 4241 - &
[7] Eaborn C., 1960, ORGANOSILICON COMPOU
[8] PREPARATION + REACTIONS OF SOME 7-SILANORBORNADIENES .I. APPROACH TO DIMETHYLSILYLENE
GILMAN, H
COTTIS, SG
ATWELL, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (08) : 1596 - &
[9] THE PREPARATION OF 1,1-DIMETHYL-2,5-DIPHENYL-1-SILACYCLOPENTADIENE
GILMAN, H
ATWELL, WH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1964, 2 (03) : 291 - 292
[10] TRIPHENYLSILYLPOTASSIUM
GILMAN, H
WU, TC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1953, 18 (06) : 753 - 764

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