SYNTHESIS AND REACTIVITY OF NEW CHALCOGEN-RICH AQUA IONS [MO3S7(H2O)(6)](4+) AND [MO3SE7(H2O)(6)](4+)

被引：12

作者：

FEDIN, VP ^{[1
]}

LAMPRECHT, GJ ^{[1
]}

SYKES, AG ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 23期

关键词：

D O I：

10.1039/c39940002685

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aqua ions [Mo3Y7(H2O)(6)](4+) (Y = S, Se) containing mu(3)-Y and mu-Y-2 core ligands have been prepared for the first-time, enabling chalcogen-transfer reactions with an H2O-soluble phosphine to generate the well-characterised [Mo3Y4(H2O)(9)](4+), reactions with Cl- to give substitution of H2O ligands (which are of two different types), and. heterometallic Sn-II addition reactions to be studied.

引用

页码：2685 / 2686

页数：2

共 17 条

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