VIBRONIC SPECTRA OF THE BENZENE CRYSTAL AT 4.2-K USING 2-PHOTON FLUORESCENCE EXCITATION

被引：35

作者：

HOCHSTRASSER, RM ^{[1
]}

KLIMCAK, CM ^{[1
]}

MEREDITH, GR ^{[1
]}

机构：

[1] UNIV PENN,RES STRUCT MAT LAB,PHILADELPHIA,PA 19104

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 02期

关键词：

D O I：

10.1063/1.437519

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The two-photon excitation spectra of benzene crystals have been determined in the range 530 to 400 nm. The spectra can be related to approximately C 2h symmetry benzene molecules. The E-type bands are all split by the crystal field as is already known for the one-photon absorption, the Raman, and the infrared spectra. The study has allowed the determination of the two-photon tensors for the eight ungerade vibrational fundamentals V11, V 14-V19 in the crystal axis system. The oriented gas transformation provides in this case an approximate diagonalization of the crystal axis based tensors. The two-photon excitation spectra are rich in two particle effects. © 1979 American Institute of Physics.

引用

页码：870 / 880

页数：11

共 36 条

[11] A NEW APPROACH TO VIBRONIC SPECTRA OF MOLECULAR CRYSTALS [J].