TOTAL PRESSURE MEASUREMENTS FOR COPPER(II) CHLORIDE PLUS METHANOL PLUS ETHANOL AT 303.15 K

被引：6

作者：

OH, SK ^{[1
]}

CAMPBELL, SW ^{[1
]}

机构：

[1] UNIV S FLORIDA,DEPT CHEM ENGN,TAMPA,FL 33620

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1995年 / 40卷 / 02期

关键词：

D O I：

10.1021/je00018a033

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Total pressure is reported as a function of liquid-phase composition for copper(II) chloride + methanol + ethanol at 303.15 K. Pressure was measured as a function of salt concentration along various lines of essentially constant methanol mole fraction (on a salt-free basis). The data were reduced by Barker's method using an empirical expression for the excess Gibbs free energy of the Liquid phase. Calculated vapor-phase compositions for the two alcohols indicate that the vapor-phase mole fraction of ethanol is increased (ethanol is salted out) by addition of copper(II) chloride to liquid mixtures of methanol and ethanol.

引用

页码：504 / 508

页数：5

共 18 条

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