PREPARATION OF MULTIPHASE BLOCK-COPOLYMERS BY REDOX POLYMERIZATION PROCESS .3. POLYMERIZATION OF METHYL-METHACRYLATE AND ACRYLAMIDE BY THE MN(III)POLY(ETHYLENE GLYCOL) REDOX SYSTEM

被引：13

作者：

CAKMAK, I ^{[1
]}

机构：

[1] KARADENIZ TECH UNIV,DEPT NAT SCI EDUC,SOGUTLU 61335,TURKEY

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1995年 / 224卷

关键词：

D O I：

10.1002/apmc.1995.052240101

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Redox-initiated free-radical polymerization of methyl methacrylate (MMA) and acrylamide (AAm) with poly(ethylene glycol) (PEG) using Mn(III) as reduction agent was carried out to yield PMMA-block-PEG-block-PMMA and AAm-block-PEG-block-AAm triblock copolymers. The principal parameters (concentration of the reactants, temperature) affecting the synthesis were examined. Block copolymers were characterized by H-1-NMR and infrared spectroscopy.

引用

页码：1 / 8

页数：8

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