ENTRAPMENT OF POLYPYRROLE CHAINS BETWEEN MOS2 LAYERS VIA AN IN-SITU OXIDATIVE POLYMERIZATION ENCAPSULATION REACTION

被引：90

作者：

WANG, L

SCHINDLER, J

THOMAS, JA

KANNEWURF, CR

KANATZIDIS, MG

机构：

[1] MICHIGAN STATE UNIV, CTR FUNDAMENTAL MAT RES, E LANSING, MI 48824 USA

[2] NORTHWESTERN UNIV, DEPT ELECT ENGN & COMP SCI, EVANSTON, IL 60208 USA

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 10期

关键词：

D O I：

10.1021/cm00058a001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidation of an aqueous pyrrole solution in the presence of single MoS2 layers resulted in the insitu intercalative encapsulation of polypyrrole into MoS2. The lamellar nanocomposite (ppy)(x)MoS2 shows an interlayer expansion of similar to 4.5 Angstrom, consistent with a monolayer of poly-pyrrole in the gallery space. This solid has a 3 orders of magnitude higher conductivity than pristine MoS2 and is a p-type conductor.

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页码：1753 / +

页数：1

相关论文

共 28 条

[1] ENCAPSULATION OF POLYMERS INTO MOS2 AND METAL TO INSULATOR TRANSITION IN METASTABLE MOS2 [J].

BISSESSUR, R ;

KANATZIDIS, MG ;

SCHINDLER, JL ;

KANNEWURF, CR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (20) :1582-1585

[2]

BISSESSUR R, 1994, MOL CRYST LIQ CRYST, V245, P249

[3] SOLID-STATE CHEMISTRY - A REDISCOVERED CHEMICAL FRONTIER [J].

DISALVO, FJ .

SCIENCE, 1990, 247 (4943) :649-655

[4] POLY(ACRYLONITRILE) CHAINS IN ZEOLITE CHANNELS - POLYMERIZATION AND PYROLYSIS [J].

ENZEL, P ;

BEIN, T .

CHEMISTRY OF MATERIALS, 1992, 4 (04) :819-824

[5] INTRAZEOLITE SYNTHESIS OF POLYTHIOPHENE CHAINS [J].

ENZEL, P ;

BEIN, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (18) :1326-1327

[6] INCLUSION-COMPOUNDS OF MOS2 [J].

GEE, MA ;

FRINDT, RF ;

JOENSEN, P ;

MORRISON, SR .

MATERIALS RESEARCH BULLETIN, 1986, 21 (05) :543-549

[7] INSITU INTERCALATIVE POLYMERIZATION OF PYRROLE IN FEOCL - A NEW CLASS OF LAYERED, CONDUCTING POLYMER INORGANIC HYBRID MATERIALS [J].

KANATZIDIS, MG ;

TONGE, LM ;

MARKS, TJ ;

MARCY, HO ;

KANNEWURF, CR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3797-3799

[8] INSITU INTERCALATIVE POLYMERIZATION CHEMISTRY OF FEOCL - GENERATION AND PROPERTIES OF NOVEL, HIGHLY CONDUCTIVE INORGANIC-ORGANIC POLYMER MICROLAMINATES [J].

KANATZIDIS, MG ;

MARCY, HO ;

MCCARTHY, WJ ;

KANNEWURF, CR ;

MARKS, TJ .

SOLID STATE IONICS, 1989, 32-3 :594-608

[9] CONDUCTIVE POLYMER - OXIDE BRONZE NANOCOMPOSITES - INTERCALATED POLYTHIOPHENE IN V2O5 XEROGELS [J].

KANATZIDIS, MG ;

WU, CG ;

MARCY, HO ;

DEGROOT, DC ;

KANNEWURF, CR .

CHEMISTRY OF MATERIALS, 1990, 2 (03) :222-224

[10] INTERCALATION CHEMISTRY OF CONDUCTING POLYMERS - NEW CRYSTALLINE MICROLAMINATE PHASES IN THE POLYANILINE FEOCL SYSTEM [J].

KANATZIDIS, MG ;

WU, CG ;

MARCY, HO ;

DEGROOT, DC ;

KANNEWURF, CR ;

KOSTIKAS, A .

ADVANCED MATERIALS, 1990, 2 (08) :364-366