ELECTROCHEMICAL SYNTHESIS AND SINTERING OF NANOCRYSTALLINE CERIUM(LV) OXIDE POWDERS

被引:166
作者
ZHOU, YC
PHILLIPS, RJ
SWITZER, JA
机构
[1] UNIV MISSOURI,DEPT CHEM,ROLLA,MO 65401
[2] UNIV MISSOURI,GRAD CTR MAT RES,ROLLA,MO 65401
关键词
D O I
10.1111/j.1151-2916.1995.tb08425.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Nanocrystalline CeO2 powders were prepared electrochemically by the cathodic electrogeneration of base, and their sintering behavior was investigated. X-ray diffraction and transmission electron microscopy revealed that the as-prepared powders were crystalline cerium(IV) oxide with the cubic fluorite structure. The lattice parameter of the electrogenerated material was 0.5419 nm. The powders consisted of nonaggregated, faceted particles, The average crystallite size was a function of the solution temperature, It increased from 10 nm at 29 degrees C to 14 nm at 80 degrees C. Consolidated powders were sintered in air at both a constant heating rate of 10 degrees C/min and under isothermal conditions. The temperature at which sintering started (750 degrees C) for nanocrystalline CeO2 powders was only about 100 degrees C lower than that of coarser-grained powders (850 degrees C). However, the sintering rate was enhanced, The temperature at which shrinkage stopped was 200 degrees-300 degrees C lower with the nanoscale powder than with micrometer-sized powders. A sintered specimen with 99.8% of theoretical density and a grain size of about 350 nm was obtained by sintering at 1300 degrees C for 2 h.
引用
收藏
页码:981 / 985
页数:5
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