A COMPARATIVE-STUDY ON THE ACTIVATION AND REACTIONS OF CH4 ON SUPPORTED METALS

被引：93

作者：

SOLYMOSI, F ^{[1
]}

ERDOHELYI, A ^{[1
]}

CSERENYI, J ^{[1
]}

机构：

[1] ATTILA JOZSEF UNIV,CTR CATALYSIS SURFACE & MAT SCI,INST SOLID STATE & RADIOCHEM,H-6701 SZEGED,HUNGARY

来源：

CATALYSIS LETTERS | 1992年 / 16卷 / 04期

关键词：

ACTIVATION OF METHANE; DECOMPOSITION OF METHANE; FORMATION OF ETHANE FROM METHANE; FORMATION OF HYDROGEN FROM METHANE; FORMATION OF SURFACE CARBON; TPR STUDY OF THE REACTION OF SURFACE CARBON; SILICA-SUPPORTED PT METALS;

D O I：

10.1007/BF00764897

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic effects of silica-supported Pt metals were tested and compared in the decomposition of methane and its conversion into higher hydrocarbons. The dissociation of methane is readily measurable at 473-673 K. The rate of initial decomposition at 523 K was the highest on Rh, but it dropped to a low value within a short contact time. The gaseous products were hydrogen and ethane in small, variable amounts. Hydrogen of the carbonaceous species formed in the decomposition led to the production of aliphatic hydrocarbons.

引用

页码：399 / 405

页数：7

共 16 条

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SOLYMOSI, F ;

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JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :8510-8519

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SOLYMOSI, F ;

KISS, J ;

REVESZ, K .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (06) :2224-2226

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SOLYMOSI, F ;

REVESZ, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (24) :9145-9147

[15]

SOLYMOSI F, IN PRESS SURF SCI

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