HYDROGEN-BONDED NETWORK FORMATION IN ORGANIC-CRYSTALS AS EFFECTED BY PERPENDICULAR AND DIVERGENT HYDROXYL-GROUPS - THE CRYSTAL-STRUCTURE OF A BISRESORCINOL DERIVATIVE OF ANTHRACENE

被引：49

作者：

KOBAYASHI, K

ENDO, K

AOYAMA, Y

MASUDA, H

机构：

[1] NAGAOKA UNIV TECHNOL,DEPT CHEM,NAGAOKA,NIIGATA 94021,JAPAN

[2] NAGOYA INST TECHNOL,DEPT APPL CHEM,SHOWA KU,NAGOYA,AICHI 466,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 49期

关键词：

CRYSTAL STRUCTURE; HYDROGEN BONDING; MOLECULAR SHEET; RESORCINOL; DIVERGENT OH GROUPS;

D O I：

10.1016/S0040-4039(00)61514-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An anthracene derivative la having two nearly perpendicular resorcinol moieties forms an extensive hydrogen-bonded network that results in enforced formation of anthracene columns. The crystal structure of 1a.(C6H6)2.(CH3CO2CH2CH3)2 contains molecular sheers composed of hydrogen-bonded polyresorcinol chains and face-to-face anthracene columns, together with large cavities which are filled with two benzene and two ethyl acetate molecules.

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页码：7929 / 7932

页数：4

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