A FACILE GENERATION OF ORGANOSAMARIUM ETA(3)-ALLYL COMPLEXES BY REDUCTIVE CLEAVAGE OF ALLYLIC ETHERS WITH (C(5)ME(5))(2)SM(THF)(N)

被引：13

作者：

TAKAKI, K

KUSUDO, T

UEBORI, S

MAKIOKA, Y

TANIGUCHI, Y

FUJIWARA, Y

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima, 724, Kagamiyama

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 09期

关键词：

D O I：

10.1016/0040-4039(95)00071-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reductive C-O bond cleavage of allylic benzyl ethers with two equivalents of (C(5)Me(5))(2)Sm(THF)(n) (n=2 or 0) takes place selectively to generate (C(5)Me(5))(2)Sm(eta(3)-allyl) complexes in high yields along with equimolar amounts of the samarium benzyloxide.

引用

页码：1505 / 1508

页数：4

共 12 条

[1] ORGANOALKALI COMPOUNDS BY RADICAL-ANION INDUCED REDUCTIVE METALATION OF PHENYL THIOETHERS [J].

COHEN, T ;

BHUPATHY, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (04) :152-161

[2] SYNTHESIS AND REACTIVITY OF ALLYL SAMARIUM COMPLEXES [J].

COLLIN, J ;

BIED, C ;

KAGAN, HB .

TETRAHEDRON LETTERS, 1991, 32 (05) :629-630

[3] REACTIVITY OF (C5ME5)2SM AND RELATED SPECIES WITH ALKENES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A SERIES OF ORGANOSAMARIUM ALLYL COMPLEXES [J].

EVANS, WJ ;

ULIBARRI, TA ;

ZILLER, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2314-2324

[4] DIVALENT LANTHANIDE DERIVATIVES IN ORGANIC-SYNTHESIS .1. MILD PREPARATION OF SMI2 AND YBI2 AND THEIR USE AS REDUCING OR COUPLING AGENTS [J].

GIRARD, P ;

NAMY, JL ;

KAGAN, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (08) :2693-2698

[5] STUDIES ON RARE-EARTH ALLYL COMPOUNDS .4. THE CRYSTAL-STRUCTURE OF [LI2(MU-C3H5)(C4H8O2)3][CE(ETA-3-C3H5)4] [J].

HUANG, ZE ;

CHEN, MQ ;

QIU, WJ ;

WU, WL .

INORGANICA CHIMICA ACTA, 1987, 139 (1-2) :203-207

[6] CARBON CARBON BOND-FORMING REACTIONS USING CERIUM METAL OR ORGANOCERIUM(III) REAGENTS [J].

IMAMOTO, T ;

KUSUMOTO, T ;

TAWARAYAMA, Y ;

SUGIURA, Y ;

MITA, T ;

HATANAKA, Y ;

YOKOYAMA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (21) :3904-3912

[7] PREPARATION AND REGIOSELECTIVE AND DIASTEREOSELECTIVE REACTIONS OF ALLYLIC ZIRCONIUM REAGENTS FROM ALLYLIC ETHER DERIVATIVES [J].

ITO, H ;

TAGUCHI, T ;

HANZAWA, Y .

TETRAHEDRON LETTERS, 1992, 33 (10) :1295-1298

[8] HIGHLY REACTIVE ORGANOLANTHANIDES - SYSTEMATIC ROUTES TO AND OLEFIN CHEMISTRY OF EARLY AND LATE BIS(PENTAMETHYLCYCLOPENTADIENYL) 4F HYDROCARBYL AND HYDRIDE COMPLEXES [J].

JESKE, G ;

LAUKE, H ;

MAUERMANN, H ;

SWEPSTON, PN ;

SCHUMANN, H ;

MARKS, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :8091-8103

[9] REDUCTIVE COUPLING OF ALLYLIC ACETATES WITH CARBONYL-COMPOUNDS BY USING PD(O)-SMI2 SYSTEM [J].

TABUCHI, T ;

INANAGA, J ;

YAMAGUCHI, M .

TETRAHEDRON LETTERS, 1986, 27 (10) :1195-1196

[10] UNUSUAL TYPE OF ORGANOLANTHANIDE COMPLEX CONTAINING ALLYL MOIETY - (ETA5-C5H5)2LNC3H5 [J].

TSUTSUI, M ;

ELY, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (12) :3551-3553

← 1 2 →