STEREOCHEMISTRY OF ORGANOMETALLIC COMPOUNDS .8. STEREOCHEMISTRY OF REDUCTION OF SOME TRICARBONYL(ARYLCYCLOALKANONE)-CHROMIUMS

被引：38

作者：

JACKSON, WR

MITCHELL, TR

机构：

[1] Department of Chemistry, Queen's University

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 09期

关键词：

D O I：

10.1039/j29690001228

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction of tricarbonyl(indan-1-one and tetral-1-one)chromiums with lithium aluminium hydride in ether and with sodium borohydride in pyridine gives almost exclusively (≥97%) the cis-tricarbonyl(arylcycloalkanol) chromium. Reduction of tricarbonyl(tetral-2-one)chromium gives up to 7% of the trans-alcohol. Steric rather than electronic factors are considered to be responsible for this stereoselectivity.

引用

页码：1228 / &

共 14 条

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