A DIRUTHENIUM COMPLEX CONTAINING AN ORTHO-METALATED BIPYRIDYL LIGAND FORMED DIRECTLY FROM [RU3(CO)12] AND PYRIDINE

被引：27

作者：

COCKERTON, BR ^{[1
]}

DEEMING, AJ ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 426卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83053-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster [RU3(CO)12] reacts with pyridine (6 mol/mol Ru3) at 120-degrees-C to give [Ru2(mu-pyr)2(CO)6] (pyr = 2-pyridyl, C5H4N) as head-to-head and head-to-tail isomers and with neat pyridine at 180-degrees-C to give [Ru2(mu-pyr)(mu-C10H7N2)(CO)5], shown by X-ray diffraction to contain a bridging orthometallated bipy ligand formed by coupling of two 2-pyridyl ligands.

引用

页码：C36 / C39

页数：4

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