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LIGAND HYPERFINE INTERACTIONS IN OXOMOLYBDENUM(V) AND OXOCHROMIUM(V) HALIDE COMPLEXES

被引：28
作者：
DALTON, LA
BEREMAN, RD
BRUBAKER, CH
机构：
[1] Department of Chemistry, Michigan State University, East Lansing
来源：
INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期
关键词：
D O I：
10.1021/ic50081a046
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ligand superhyperfine interactions have been observed in esr spectra of solutions, frozen glasses, and diamagnetically diluted single crystals of MoOBr52-, MoOI52-, and CrOCL52-. The results indicate considerable covalency in metal-ligand bonding. In the molybdenum and chromium complexes the superhyperfine tensors indicate π bonding involving the metal dxy orbital and p orbitals of the four equatorial ligands. In these d1- complexes the ligand orbital involved in bonding possesses some s character. © 1969, American Chemical Society. All rights reserved.
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页码：2477 / &
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