TRANSITION-METAL FULVENE COMPLEXES .14. CRYSTAL AND MOLECULAR-STRUCTURE OF FERROCENYLDIPHENYLCARBENIUM TETRAFLUOROBORATE - FULVENE-IRON COMPLEX

被引：139

作者：

BEHRENS, U

机构：

[1] Institut für Anorganische, Angewandte Chemie der Universität Hamburg, D 2000 Hamburg 13

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)85878-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of ferrocenyldiphenylcarbenium tetrafluoroborate has been determined by single crystal X-ray analysis. The compound crystalizes in the orthorhombic space group P21cn with lattice constants a 905.1(3), b 1087.0(7), c 1964.4(9) pm; Z 4. The final R index for 1525 observed reflections of non-zero weight (F ≫ 2 σ) is 0.040. The molecule can be described as a fulvenecyclopentadienyliron cation with the fulvene exocyclic double bond bent to the iron (angle 20.7°) and an FeCexo distance of 271.5 pm. © 1979.

引用

页码：89 / 98

页数：10

共 19 条

[11] LUBKE B, UNPUBLISHED
[12] Lupan S., 1972, ANGEW CHEM, V84, P1104
[13] MAIN P, MULTAN 78
[14] PETTIT R, 1976, CARBONIUM IONS, V5, P2293
[15] ALPHA-METALLOCENYL CARBONIUM IONS
RICHARDS, JH
HILL, EA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (13) : 3484 - 3485
[16] SHELDRICK G, 1975, PROGRAMMS CRYSTAL ST
[17] CRYSTAL-STRUCTURE OF FERROCENYLDIPHENYLCYCLOPROPENIUM TETRAFLUOROBORATE, A STABLE CARBONIUM-ION SALT
SIME, RL
SIME, RJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (03) : 892 - 896
[18] C-13 NMR SPECTROSCOPIC STUDY OF FERROCENYLMETHYL CARBONIUM-IONS
WILLIAMS, GH
TRAFICAN.DD
SEYFERTH, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 60 (02) : C53 - C56
[19] 1974, GMELINS HDB ANORGA A, V14, P348

← 1 2 →