OPTICALLY DETECTED MAGNETIC-RESONANCE OF THE LUMINESCENT STATE IN NAFCU+

被引：8

作者：

VANTOL, J ^{[1
]}

VANDERWAALS, JH ^{[1
]}

机构：

[1] LEIDEN UNIV,CTR STUDY EXCITED STATES MOLEC,HUYGENS LAB,POB 9504,2300 RA LEIDEN,NETHERLANDS

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 194卷 / 4-6期

关键词：

D O I：

10.1016/0009-2614(92)86053-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Optically detected electron paramagnetic resonance (OD-EPR) spectra at 22.9, 75.0, and 94.9 GHz of the luminescent state of Cu+ ions in NaF are reported. The EPR spectra do not support the current T1g(3E(g), 3d(9)4s) "atomic" assignment of the luminescent state. but point to a paramagnetic species with g values in the range of 2.0-2.5, a very small or no zero-field splitting and a spin density in thc Cu 4s orbital lower than 0.04.

引用

页码：288 / 296

页数：9