PHOTOOXIDATION OF ORGANIC-COMPOUNDS IN THE PRESENCE OF TITANIUM-DIOXIDE - DETERMINATION OF THE EFFICIENCY

被引：116

作者：

SABIN, F

TURK, T

VOGLER, A

机构：

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1992年 / 63卷 / 01期

关键词：

D O I：

10.1016/1010-6030(92)85157-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photo-oxidation of 23 compounds (benzene, haloaromatics, chloroalkenes, haloalkanes, bis-(2-chloroethyl)ether, 1-hydroxyethane-1, 1-diphosphonate and ethylenediamine-N,N,N',N'-acetic acid) in aqueous solution with titanium dioxide as the photocatalyst was investigated. The plots of photo-oxidation rate vs. irradiation time were analysed on the basis of a simple kinetic model for homogeneous reactions. This model yielded formal rate constants which serve as a general measure for the efficiency of photo-oxidation.

引用

页码：99 / 106

页数：8

共 36 条

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