STRUCTURE AND REACTIONS OF METHYLENESULFUR TETRAFLUORIDE

被引：32

作者：

BOCK, H

BOGGS, JE

KLEEMANN, G

LENTZ, D

OBERHAMMER, H

PETERS, EM

SEPPELT, K

SIMON, A

SOLOUKI, B

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-6900 HEIDELBERG 1,FED REP GER

[2] UNIV TUBINGEN,INST PHYS & THEORET CHEM,D-7400 TUBINGEN 1,FED REP GER

[3] MAX PLANCK INST FESTKORPERFORSCH,D-7000 STUTTGART 80,FED REP GER

[4] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

[5] UNIV FRANKFURT,INST ANORGAN CHEM,D-6000 FRANKFURT 50,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the trigonal‐bipyramidal species H2CSF4 1 the H atoms are located in the plane of the axial F atoms (low‐temperature crystal structure analysis, electron diffraction). The PE spectrum confirms that the resonance structure having a double bond has greater weight than in other ylides. 1 is exceptionally stable thermally, but highly reactive (addition to the polar CS bond, CH2 transfer). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：944 / 945

页数：2