DIASTEREOSELECTIVE ALKYLATION OF CHIRAL DERIVATIVES OF ACETOACETIC ACID

被引：13

作者：

MORENOMANAS, M ^{[1
]}

SEBASTIAN, RM ^{[1
]}

VALLRIBERA, A ^{[1
]}

MOLINS, E ^{[1
]}

机构：

[1] CSIC,INST CIENCIA MAT,E-08193 CERDANYOLA,SPAIN

来源：

TETRAHEDRON | 1995年 / 51卷 / 39期

关键词：

D O I：

10.1016/0040-4020(95)00643-M

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-acetoacetyl-(S)-4-benzyloxazolidin-2-one and N-acetoacetyl-(R)-bornane-10,2-sultam are alkylated at the C-alpha of the acetoacetyl moiety with significant diastereoisomeric excesses. The diastereoisomers are in general easily separable and configurationally fairly stable.

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收藏

页码：10795 / 10800

页数：6

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