ENANTIOMER SEPARATION OF ALPHA-CAMPHOLENE AND FENCHOLENE DERIVATIVES BY CAPILLARY GAS-CHROMATOGRAPHY ON PERMETHYLATED CYCLODEXTRIN PHASES .1. COMPOUNDS SEPARABLE WITH SINGLE COLUMNS

被引:16
作者
REINHARDT, R
STEINBORN, A
ENGEWALD, W
ANHALT, K
SCHULZE, K
机构
[1] UNIV LEIPZIG,INST ANALYT CHEM,DEPT CHEM,D-04103 LEIPZIG,GERMANY
[2] UNIV LEIPZIG,INST ORGAN CHEM,DEPT CHEM,D-04103 LEIPZIG,GERMANY
[3] UNIV LEIPZIG,INST PHARMACOL & TOXICOL,DEPT MED,D-04107 LEIPZIG,GERMANY
关键词
D O I
10.1016/0021-9673(94)01072-M
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
alpha-Campholene and fencholene derivatives are compounds with interesting odour properties, e.g. sandalwood and woody notes. They have one (derived from the initial product, alpha-pinene) or several stereogenic centres. The stereoisomers of these compounds may have different odour properties; therefore, analysis methods are developed for the complete separation of the diastereomers and enantiomers. It is shown that the alcohols with one stereogenic centre as well as of the esters and ethers of alpha-campholene and fencholene derivatives with two stereogenic centres can be separated on permethylated alpha- und beta-cyclodextrins dissolved in polysiloxanes. Factors influencing the separation are discussed.
引用
收藏
页码:475 / 484
页数:10
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