CONTRIBUTION TO THE ISOLATION AND CHARACTERIZATION OF BUCKMINSTERFULLERENES

被引：34

作者：

DIACK, M

HETTICH, RL

COMPTON, RN

GUIOCHON, G

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

[2] OAK RIDGE NATL LAB,CHEM PHYS SECT,OAK RIDGE,TN 37831

[3] OAK RIDGE NATL LAB,DIV ANALYT CHEM,OAK RIDGE,TN 37831

来源：

ANALYTICAL CHEMISTRY | 1992年 / 64卷 / 18期

关键词：

D O I：

10.1021/ac00042a020

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Buckminsterfullerenes are extracted from samples of the soot generated by a high-energy electric arc discharge between two graphite electrodes. A rapid and quantitative procedure based on ultrasonic extraction was developed. It permits the evaluation of adjustments made in the different parameters involved in the synthesis process by relating them to the mass of the fractions obtained. Purified samples of C60, C70, and C84 are obtained by high-performance liquid chromatography, using chemically bonded C18 silica as the stationary phase and n-hexane as the mobile phase. The purified fullerenes were identified by laser desorption Fourier-transform mass spectrometry and verified by UV-visible spectroscopy. The results are consistent with those previously reported.

引用

页码：2143 / 2148

页数：6