A PHASE REFERENCE PROCEDURE FOR INTERPRETATION OF IMPEDANCE SPECTROSCOPY EXPERIMENTS

被引：16

作者：

GEBHARDT, O

机构：

[1] Laboratory for Materials and Nuclear Processes, Paul Scherrer Institute

来源：

ELECTROCHIMICA ACTA | 1993年 / 38卷 / 05期

关键词：

IMPEDANCE SPECTROSCOPY; BODE DIAGRAMS; ZIRCONIUM OXIDES; DISSIPATION; NETWORK SYNTHESIS;

D O I：

10.1016/0013-4686(93)80231-N

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new approach for interpreting of impedance spectroscopy (IMS) data has been developed. It is shown by the generalized logarithm of impedance vs. logarithm of frequency (Bode) diagrams, that specific recharging processes in different layers of oxide scales can be characterized by different slopes of the impedance graph. Equivalent electrical networks can be designed which contain the minimum of circuit elements to fit the significant details in the experimentally obtained Bode diagram. The thickness of the total oxide and the thickness of intrinsic oxide scales can be determined. For the total oxide thickness a good agreement with other methods is obtained.

引用

页码：633 / 641

页数：9

共 22 条

[1] TRANSMISSION ELECTRON-MICROSCOPY OF ION-THINNED OXIDES FORMED DURING CORROSION OF ZIRCALOY-4 [J].