1,9-DISUBSTITUTED PHENALENES .4. PREPARATION AND PROPERTIES OF 1,9-DIHETERO-SUBSTITUTED PHENALENYL CATIONS

被引：17

作者：

FRANZ, KD ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV, RES SCH CHEM, CANBERRA 2600, ACT, AUSTRALIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 10期

关键词：

D O I：

10.1021/jo01324a026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of new 1, 9-dihetero-substituted (OR, SR, NR2) phenalenes and phenalenyl cations is reported and their 1H and 13C NMR and UV/Vis spectra together with their redox potentials are discussed. Shifts of the 13C resonances of the ring atoms of the cations indicate a close relationship with the parent compound phenalenyl. This can also be seen fr6m the existence of the free radical and the anionic species, which can be generated electrochemically. © 1979, American Chemical Society. All rights reserved.

引用

页码：1704 / 1708

页数：5