POLYMER BINDING ULTRAFILTRATION AS A METHOD FOR CONCENTRATION AND SEPARATION OF METALS

被引：93

作者：

VOLCHEK, K ^{[1
]}

KRENTSEL, E ^{[1
]}

ZHILIN, Y ^{[1
]}

SHTEREVA, G ^{[1
]}

DYTNERSKY, Y ^{[1
]}

机构：

[1] DI MENDELEEV CHEM ENGN INST,MOSCOW 125820,RUSSIA

来源：

JOURNAL OF MEMBRANE SCIENCE | 1993年 / 79卷 / 2-3期

关键词：

THEORY; ULTRAFILTRATION; WATER TREATMENT; SELECTIVE BINDING; POLYELECTROLYTES;

D O I：

10.1016/0376-7388(93)85120-L

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A hybrid method for the separation and concentration of metals was investigated. The method includes binding of target metal ions by a polyelectrolyte into water soluble macromolecular compounds and subsequent membrane separation of the bound metals from unbound components. The influence of the composition and pH of the solution on the effectiveness of the separation process was studied. A mathematical model of this process was developed. The competitive character of interaction of metals with a polymer, metal ion hydrolysis and other phenomena were taken into account in the model. Optimum process conditions were determined and applied to the solution of particular problems such as the recovery of valuable metals from sea water and treatment of industrial wastes.

引用

页码：253 / 272

页数：20

共 35 条

[11] LIQUID-PHASE POLYMER-BASED RETENTION, A NEW METHOD FOR SEPARATION AND PRECONCENTRATION OF ELEMENTS
GECKELER, KE
BAYER, E
SPIVAKOV, BY
SHKINEV, VM
VOROBEVA, GA
[J]. ANALYTICA CHIMICA ACTA, 1986, 189 (02) : 285 - 292
[12] Gembitsky P.A., 1971, POLYETHYLENIMINE
[13] GRIGOREV NB, 1982, ELEKTROKHIMIYA, V18, P569
[14] KICHIK VA, 1985, ATOM ENERG, V58, P272
[15] LE VT, 1989, 2ND P INT C SEP SCI, P640
[16] LINDSEY EE, 1978, OWRT A057MASS U MASS
[17] Linke WF, 1958, SOLUBILITIES INORGAN, VI
[18] LINKE WF, 1965, SOLUBILITIES INORGAN, V2
[19] THE ROLE OF MACROMOLECULAR ADSORPTION IN FOULING OF ULTRAFILTRATION MEMBRANES
MATTHIASSON, E
[J]. JOURNAL OF MEMBRANE SCIENCE, 1983, 16 (DEC) : 23 - 36
[20] MICHAELS AS, 1968, ADV SEPARATION PURIF

← 1 2 3 4 →