THE REACTIVITY OF SPECTROSCOPICALLY DETECTED PEROXY COMPLEXES OF IRON PORPHYRINS

被引：55

作者：

BALCH, AL

机构：

[1] Department of Chemistry, University of California, Davis

来源：

INORGANICA CHIMICA ACTA | 1992年 / 198卷

关键词：

D O I：

10.1016/S0020-1693(00)92372-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination of alkyl peroxides by heme proteins is an important step in the functioning of several enzymes, (for example, peroxidases, cytochrome P450, estrogen synthase). Generally the reaction of peroxides with iron porphyrins in the absence of a proton results in the destruction of both porphyrin and peroxide. However, three distinct intermediates involving coordination of peroxides to iron porphyrins can be identified using spectroscopic techniques. The formation, spectroscopic characteristics and chemical behavior of these reactive intermediates are reviewed here.

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页码：297 / 307

页数：11

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