DEHYDROGENATIVE CONDENSATION OF HYDROSILANES CATALYZED BY AN ORGANONEODYMIUM COMPLEX

被引：50

作者：

SAKAKURA, T ^{[1
]}

LAUTENSCHLAGER, HJ ^{[1
]}

NAKAJIMA, M ^{[1
]}

TANAKA, M ^{[1
]}

机构：

[1] TONEN CHEM CORP, CHUO KU, TOKYO 104, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 06期

关键词：

D O I：

10.1246/cl.1991.913

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dehydrogenative condensation of trihydrosilanes is catalyzed by (C5Me5) 2NdCH (SiMe3) 2 to give polysilanes in high yields. In the polymerization of PhSiH3, molecular weight of the polymer becomes higher with an increase of the reaction temperature. Cyclic structures are indicated for oligomers larger than pentamers by FD-MS spectroscopy.

引用

页码：913 / 916

页数：4