USE OF FUROIN AS PROBE MOLECULE FOR THE INVOLVEMENT OF SINGLET OXYGEN IN AQUEOUS-PHASE PHOTOINDUCED TRANSFORMATIONS

被引：10

作者：

AGUER, JP

RICHARD, C

机构：

[1] Laboratoire de Photochimie Moléculaire et Macromoléculaire, URA CNRS 433, Université Blaise Pascal

来源：

TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY | 1993年 / 39卷 / 3-4期

关键词：

MOLECULAR PROBE; PHOTOCHEMISTRY; SINGLET OXYGEN; FUROIN; HYDROXYL RADICALS;

D O I：

10.1080/02772249309357920

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The reactivity of furoin with various photogenerated reactive species has been studied. The oxidation of furoin by hydroxyl radicals, produced by photolysis of dilute hydrogen peroxide solutions at 253.7 nm, leads to 5-hydroxyfuranone, furaldehyde and furoic acid. It was found k5 = 1.3 x 10(10) M-1.s-1. The oxygenation of furoin by singlet oxygen, obtained by rose bengal photosensitization, gives rise to 5-hydroxyfuranone and 1-furanyl-2-dihydroxyethanone with k2 = 1.8 x 10(8) M-1.s-1. Superoxide anion generated by photolysis of concentrated hydrogen peroxide solutions and RO, obtained by photolysis of 4,4'-azobis-4 cyanovaleric acid in the presence of oxygen reacts with furoin with a very low rate constant. Thus, furoin can be used as a test molecule for hydroxyl radicals and singlet oxygen involvements in aqueous phase photoinduced transformations.

引用

页码：217 / 227

页数：11

共 15 条

[1] REACTIVITY OF HO2/O-2 RADICALS IN AQUEOUS-SOLUTION [J].