ELECTROCHEMICAL FLUORINATIVE ALPHA-CLEAVAGE OF CYCLIC-KETONES - SYNTHESIS OF FLUOROCARBOXYLIC ACID-ESTERS

被引:32
作者
HARA, S
CHEN, SQ
HATAKEYAMA, T
FUKUHARA, T
SEKIGUCHI, M
YONEDA, N
机构
[1] Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo
关键词
D O I
10.1016/0040-4039(95)01308-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The electrochemical oxidation of 2,2-disubstituted cyclic ketones was carried out using Et(3)N-5HF as the electrolyte. The selective cleavage of the carbon-carbon bond between the carbonyl carbon and substituted alpha-carbon took place and fluorocarboxylic acid esters (2) were obtained in good yields after the esterification of the resulting fluoroacyl fluorides (1).
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页码:6511 / 6514
页数:4
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