VISIBLE LIGHT-ASSISTED DEHYDROGENATION OF ALKANES CATALYZED BY THE RHCL(CH2=CH2)(PME3)2-H-NU SYSTEM

被引：25

作者：

SAKAKURA, T

ABE, F

TANAKA, M

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 02期

关键词：

D O I：

10.1246/cl.1991.297

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkanes are catalytically dehydrogenated to alkenes with RhCl(CH2 = CH2)(PMe3)2 (lambda-max 416 nm) under visible light irradiation in the presence of ethylene. The reaction proceeds smoothly even at room temperature; the quantum yield of cyclooctane dehydrogenation was 0.10 at 25-degrees-C.

引用

页码：297 / 298

页数：2

共 7 条

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