REMARKABLE EFFECTS OF METAL-IONS AND AXIAL BASES ON CATALYTIC AND ASYMMETRIC OXIDATION OF SIMPLE OLEFINS WITH A TWIN-CORONET PORPHYRIN

被引：16

作者：

NARUTA, Y

TANI, F

MARUYAMA, K

机构：

[1] Department of Chemistry, Faculty of Science, Kyoto University, Sakyo-ku, Kyoto

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(00)60964-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Effect of central metals and oxidants on the catalytic and asymmetric epoxidation of simple olefins was evaluated with a chiral binaphthalene-linked twin-coronet porphyrin catalyst, whose Mn derivative gave superior ees of resultant epoxide than the corresponding Fe derivative.

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页码：6323 / 6326

页数：4

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