PERFORMANCE OF A PROTONATED CO-CONTAINED SILICATE CATALYST FOR NO REDUCTION IN EQUIVALENT CONDITIONS TO DIESEL-ENGINE EXHAUST

被引：24

作者：

INUI, T

HIRABAYASHI, T

IWAMOTO, S

机构：

[1] Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, 606-01, Sakyo-ku

来源：

CATALYSIS LETTERS | 1994年 / 27卷 / 3-4期

关键词：

CO-SILICATE; DENOX CATALYST; DIESEL ENGINE EXHAUST; PRODUCT INHIBITION; CATALYST STABILITY;

D O I：

10.1007/BF00813912

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Effects of co-existence of H2O, CO2, and SO2 in the reaction gas on the catalytic performance of cobalt containing silicate having ZSM-5 (MFI) structure (Co-silicate) were studied. Water vapor retarded only the hydrocarbon conversion to CO2 but no effect was observed on NO conversion. Addition of CO2 or SO2 did not affect the reaction. The stability of H-Co-silicate against H2O, CO2, and SO2 was ascribed to the state of metallic active species which were stabilized by incorporation into the high siliceous MFI structure.

引用

页码：267 / 272

页数：6

共 20 条

[11] DEACTIVATION IN CU-ZSM-5 LEAN-BURN CATALYSTS [J].

KHARAS, KCC ;

ROBOTA, HJ ;

LIU, DJ .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1993, 2 (2-3) :225-237

[12] SELECTIVE REDUCTION OF NO WITH PROPYLENE ON FE-SILICATE CATALYSTS [J].

KIKUCHI, E ;

YOGO, K ;

TANAKA, S ;

ABE, M .

CHEMISTRY LETTERS, 1991, (06) :1063-1066

[13] SELECTIVE CATALYTIC REDUCTION OF NOX WITH METHANE OVER METAL EXCHANGED ZEOLITES [J].

LI, YJ ;

ARMOR, JN .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1993, 2 (2-3) :239-256

[14]

MATSUMOTO S, 1993, FEB INT FOR ENV CAT, P61

[15] CATALYTIC REMOVAL OF NITROGEN MONOXIDE OVER RARE-EARTH ION-EXCHANGED ZEOLITES IN THE PRESENCE OF PROPENE AND OXYGEN [J].

MISONO, M ;

KONDO, K .

CHEMISTRY LETTERS, 1991, (06) :1001-1002

[16] PERFORMANCE OF PLATINUM-GROUP METAL-CATALYSTS FOR THE SELECTIVE REDUCTION OF NITROGEN-OXIDES BY HYDROCARBONS [J].

OBUCHI, A ;

OHI, A ;

NAKAMURA, M ;

OGATA, A ;

MIZUNO, K ;

OHUCHI, H .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1993, 2 (01) :71-80

[17] IRON ION-EXCHANGED ZEOLITE - THE MOST ACTIVE CATALYST AT 473-K FOR SELECTIVE REDUCTION OF NITROGEN MONOXIDE BY ETHENE IN OXIDIZING ATMOSPHERE [J].

SATO, S ;

HIRABAYASHI, H ;

YAHIRO, H ;

MIZUNO, N ;

IWAMOTO, M .

CATALYSIS LETTERS, 1992, 12 (1-3) :193-200

[18] CU-ZSM-5 ZEOLITE AS HIGHLY-ACTIVE CATALYST FOR REMOVAL OF NITROGEN MONOXIDE FROM EMISSION OF DIESEL-ENGINES [J].

SATO, S ;

YOSHIHIRO, Y ;

YAHIRO, H ;

MIZUNO, N ;

IWAMOTO, M .

APPLIED CATALYSIS, 1991, 70 (01) :L1-L5

[19]

SUGANUMA F, 1993, SHOKUBAI, V35, P114

[20]

YOGO K, 1993, CHEM LETT, P239

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