HETERONUCLEAR COMPLEXES CONTAINING CUCO(CO)4 STRUCTURAL UNITS AND NITROGEN LIGANDS

被引：10

作者：

ACHTERNBOSCH, M ^{[1
]}

BRAUN, H ^{[1
]}

FUCHS, R ^{[1
]}

KLUFERS, P ^{[1
]}

SELLE, A ^{[1
]}

WILHELM, U ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST ANORGAN CHEM,ENGESSERSTR GEBAUDE 3045,W-7500 KARLSRUHE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 07期

关键词：

D O I：

10.1002/anie.199007831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

“Semibridging” CO groups characterize complexes 1–3, all of which are ultimately formed from CuCl and Na[Co(CO)4] in the presence of increasing concentrations of ammonia. The structure of the Cu2Co2 complex 2 is shown on the right; the arrows indicate which bonds are cleaved by NH3 to form 3. Analogous cleavage of 1 results in formation of 2. (Formula Presented.) (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：783 / 785

页数：3