The bubble pressures and saturated liquid densities of mixtures of R 22 and R 114 have been measured with a static and synthetic method with a variable-volume cell. The results for five different compositions (100, 75, 50, 25, and O mol% R 22) cover the temperature range from 310 to 400 K. The experimental data for both pure components are compared with literature data, showing the reliability of the present results. The system shows positive deviations from Raoult's law at temperatures below 340 K and the deviations increase with decreasing temperature. The 25 mol% R 22 mixture shows the maximum non-ideality.