REGIOSELECTIVE HYDROSILYLATION-DESILYLATION - CONVENIENT PREPARATION OF A 2-(TRIMETHYLSILYL)-1-ALKENE

被引：31

作者：

HUDRLIK, PF ^{[1
]}

SCHWARTZ, RH ^{[1
]}

HOGAN, JC ^{[1
]}

机构：

[1] RUTGERS STATE UNIV, SCH CHEM, NEW BRUNSWICK, NJ 08903 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 01期

关键词：

D O I：

10.1021/jo01315a040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinylsilanes are compounds of increasing importance in organic synthesis,3 in part because they undergo electrophilic substitution reactions with a variety of reagents and thus serve as vinyl anion equivalents3, 4 and in part because the derived α,β-epoxysilanes can serve as versatile vinyl cation equivalents.5 A number of methods for the synthesis of vinylsilanes have been reported,6, 7 but few of these are suited for the preparation of 2-(trimethylsilyl)-1-alkenes.7. © 1979, American Chemical Society. All rights reserved.

引用

页码：155 / 157

页数：3

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