THE FIRST COMPLEX WITH AN M(3)TE(7) CLUSTER CORE - SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURE OF CS-4.5[MO-3(MU(3)-TE)(MU(2)-TE-2)(3)(CN)(6)]I-2.5-CENTER-DOT-3H2O

被引：31

作者：

FEDIN, VP

IMOTO, H

SAITO, T

MCFARLANE, W

SYKES, AG

机构：

[1] UNIV TOKYO,SCH SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 21期

关键词：

D O I：

10.1021/ic00125a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first complex with an M(3)Te(7) cluster core, [Mo-3(mu(3)-Te)(mu(2)-Te-2)(3)(CN)(6)](2-), has been synthesized by the extrusion reaction of the solid-state product of the high-temperature reaction of molybdenum, tellurium, and iodine with aqueous cyanide. Short Te...I contacts play an important role in the crystal packing of the title compound and lead to the formation of quasi-two-dimensional layers. Reactivity of tellurium-rich Mo3Te7 cluster complexes in chalcogen-transfer reactions is drastically different from that of sulfide and selenide analogs.

引用

页码：5097 / &

共 41 条

[31]

Pauling L., 1960, NATURE CHEM BOND

[32] NEW MOLYBDENUM (II)THIOCHLORIDES, MO6CL10Y(Y=S,SE,TE) - STRUCTURE AND MAGNETIC AND ELECTRICAL-PROPERTIES [J].