ALPHA-ARYLATION VS ALPHA-ARYLHYDRAZONYLATION OF ALKYL ARYL KETONES WITH ARYLAZO TERT-BUTYL SULFIDES

被引：35

作者：

DELLERBA, C ^{[1
]}

NOVI, M ^{[1
]}

PETRILLO, G ^{[1
]}

TAVANI, C ^{[1
]}

机构：

[1] UNIV GENOA,IST CHIM ORGAN,CNR,CTR STUDIO CHIM COMPOSTI CICLOALIFAT & AROMAT,CORSO EUROPA 26,I-16132 GENOA,ITALY

来源：

TETRAHEDRON | 1993年 / 49卷 / 01期

关键词：

D O I：

10.1016/S0040-4020(01)80522-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Potassium enolates of alkyl aryl ketones react selectively in DMSO with phenylazo 1a and 4-methylphenylazo tert-butyl sulfide 1b undergoing respectively effective alpha-phenylation via S(RN)1 and alpha-(4-methylphenyl)hydrazonylation via elimination-addition.

引用

页码：235 / 242

页数：8

共 38 条

[31] BENZOCYCLOBUTENE AND 2-PHENYLETHYL CHLORIDE AS ALKYLATING-AGENTS IN FRIEDEL CRAFTS REACTION [J].