THERMOLYSIS OF SOME 4-SUBSTITUTED AND 5-SUBSTITUTED ISOTHIAZOLES IN GAS-PHASE

被引：6

作者：

CASTILLO, GE ^{[1
]}

BERTORELLO, HE ^{[1
]}

机构：

[1] UNIV NACL CORDOBA,FAC CIENCIAS QUIM,DEPT QUIM ORGAN,CORDOBA,ARGENTINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1978年 / 04期

关键词：

D O I：

10.1039/p19780000325

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthesis of thioketens is described by the gas-phase thermolysis of the 4- or 5-substituted isothiazoles (1) - (3). It is believed that the reactions may involve thioxocarbenes (8) orthiirens (9) as short-lived intermediates. A scheme for the reaction mechanism is proposed in the light of results of chemical trapping experiments and the activation parameters found.

引用

页码：325 / 328

页数：4

共 29 条

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