THE 1ST STRUCTURALLY CHARACTERIZED HOMOLEPTIC THORIUM ALKOXIDE - X-RAY CRYSTAL-STRUCTURE OF [TH(OCH(PR-ISO)2)4]2, AND NMR EVIDENCE FOR A MONOMER DIMER EQUILIBRIUM

被引:20
作者
CLARK, DL [1 ]
HUFFMAN, JC [1 ]
WATKIN, JG [1 ]
机构
[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405
关键词
D O I
10.1039/c39920000266
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and X-ray crystal structure of the dimeric five-coordinate homoleptic thorium alkoxide [Th(OCHPr(i)2)4]2, the first X-ray structural characterisation of a homoleptic thorium alkoxide complex, are reported: H-1 NMR findings evidence an equilibrium between the dimer [Th(OCHPr(i)2)4]2 and its monomer [Th(OCHPr(i)2)4].
引用
收藏
页码:266 / 268
页数:3
相关论文
共 33 条