THE SYNTHESIS AND CHARACTERIZATION OF NORBORNYLSILASESQUIOXANES

被引：41

作者：

HAMBLEY, TW ^{[1
]}

MASCHMEYER, T ^{[1
]}

MASTERS, AF ^{[1
]}

机构：

[1] UNIV SYDNEY,DEPT INORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1992年 / 6卷 / 03期

关键词：

SILASEQUIOXANES; SYNTHESIS; CHARACTERIZATION; NMR SPECTRA; INFRARED SPECTRA; MASS SPECTRA;

D O I：

10.1002/aoc.590060302

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Norbornene reacts with trichlorosilane to generate norbornyltrichlorosilane in high yield. The slow hydrolysis of norbornyltrichlorosilane in acetone yields incompletely condensed norbornylsilasesquioxanes. The compound C42H70O11Si6 can be isolated from this reaction. On the basis of elemental analyses, H-1, C-13 and Si-29 NMR, mass spectroscopy, infrared spectroscopy, and crystallographic analysis, C42H70O11Si6 is formulated as [(C7H11)6Si6O7(OH)4], with the Si6O7 framework being composed of two perpendicular Si4O4 planes sharing an edge. [(C7H11)6Si6O7(OH)4] is a putative model of vicinal [Si(OH)]2 sites on the surface of partially dehydroxylated silica.

引用

页码：253 / 260

页数：8

共 43 条

[31] SUPPORTED CHROMIUM CATALYSTS FOR ETHYLENE POLYMERIZATION [J].

MCDANIEL, MP .

ADVANCES IN CATALYSIS, 1985, 33 :47-98

[32] THE STRUCTURE OF AFWILLITE, CA3(SIO3OH)2.2H2O [J].

MEGAW, HD .

ACTA CRYSTALLOGRAPHICA, 1952, 5 (04) :477-491

[33] INFRARED STUDIES OF REACTIONS ON OXIDE SURFACES .1. BORON-TRIFLUORIDE ON SILICA [J].

MORROW, BA ;

DEVI, A .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1972, 68 :403-&

[34]

Pope M.T., 1983, HETEROPOLY ISOPOLY O

[35] DEUTERATION OF ORGANOTIN MOLECULES IN SN-119 NMR .2. KARPLUS TYPE OF RELATIONSHIP OF (3)J(SND) AND STEREOCHEMISTRY OF DEUTERO-STANATION OF SOME ETHYLENE HYDROCARBONS [J].

QUINTARD, JP ;

DEGUEILCASTAING, M ;

BARBE, B ;

PETRAUD, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 234 (01) :41-61

[36]

SANTINI CC, 1987, J CHEM SOC CHEM COMM, V4, P512

[37] THERMAL REARRANGEMENT OF BRANCHED-CHAIN METHYLPOLYSILOXANES [J].

SCOTT, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (03) :356-358

[38]

Shriver D.F, 1969, MANIPULATION AIR SEN

[39] SI-29 NMR-STUDY OF DEHYDRATED REHYDRATED SILICA-GEL USING CROSS POLARIZATION AND MAGIC-ANGLE SPINNING [J].

SINDORF, DW ;

MACIEL, GE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (06) :1487-1493

[40] INFRARED SPECTRA-STRUCTURE CORRELATIONS FOR ORGANOSILICON COMPOUNDS [J].

SMITH, AL .

SPECTROCHIMICA ACTA, 1960, 16 (1-2) :87-105

← 1 2 3 4 5 →