EVIDENCE FOR A NONCLASSICAL STRUCTURE OF A 1,6-METHANO[10]ANNULENE - A CRYOGENIC C-13 CPMAS NMR-STUDY OF THE 11,11-DIMETHYL DERIVATIVE

被引：11

作者：

DORN, HC

YANNONI, CS

LIMBACH, HH

VOGEL, E

机构：

[1] IBM CORP,ALMADEN RES CTR,SAN JOSE,CA 95120

[2] FREE UNIV BERLIN,FACHBEREICH CHEM,D-14195 BERLIN,GERMANY

[3] UNIV COLOGNE,INST ORGAN CHEM,W-5000 COLOGNE 41,GERMANY

[4] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 45期

关键词：

D O I：

10.1021/j100096a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High-resolution C-13 NMR spectra obtained using cryogenic CPMAS methodology at temperatures as low as 10 K suggest that the structure of 11,11-dimethyl-1,6-methano[10]annulene is nonclassical.

引用

页码：11628 / 11629

页数：2

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