POLYEPIIODOHYDRIN

被引：17

作者：

SCHACHT, E ^{[1
]}

BAILEY, D ^{[1
]}

VOGL, O ^{[1
]}

机构：

[1] UNIV MASSACHUSETTS,AMHERST,MA 01003

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1978年 / 16卷 / 09期

关键词：

D O I：

10.1002/pol.1978.170160921

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In the reported experiments, polyepiiodohydrin was prepared from polyepichlorohydrin by the Finkelstein reaction with sodium iodide in butanone. An 88% degree of replacement of chlorine by iodine was obtained. The reaction of iodides with polyepichlorohydrin was accompanied by a substantial drop in molecular weight. The copolymer, which contains eight epiiodohydrin units per epichlorohydrin unit, has a glass transition temperature of 1 degree C and a density of 2. 2 g/cm**3. Properties of epiiodohydrin homopolymer were estimated by extrapolation of copolymer data.

引用

页码：2343 / 2351

页数：9

共 31 条

[11]

JURISCH MJ, 1972, Patent No. 3640766

[12]

KURENGINA TN, 1970, Patent No. 271013

[13]

LORENSEN LE, 1967, Patent No. 3331788

[14]

MARKLOW RJ, 1966, Patent No. 1031039

[15] SYNTHESIS OF POLY-3,3-BIS(CHLOROMETHYL)-OXACYCLOBUTANE (PENTON) DERIVATIVES [J].

MINOURA, Y ;

SHIINA, K ;

YOSHIKAW.K .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1967, 5 (11PA) :2843-&

[16] REACTION OF POLYEPICHLOROHYDRIN WITH MAGNESIUM AND GRIGNARD REAGENTS [J].

MINOURA, Y ;

HIRONAKA, H ;

KASABO, T ;

UENO, Y .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (9PA1) :2505-&

[17] SYNTHESIS AND PHOTOSENSITIVE PROPERTIES OF PHOTOCROSSLINKABLE POLY(GLICIDYL CINNAMATE) [J].

NISHIKUBO, T ;

ICHIJYO, T ;

TAKAOKA, T .

NIPPON KAGAKU KAISHI, 1973, (01) :35-39

[18]

NISHIKUBO T, 1973, Patent No. 7303219

[19]

POOT AL, 1970, Patent No. 2007168

[20]

Redmore D., 1970, United States Patent, Patent No. 3531514

← 1 2 3 4 →