VIBRATIONAL-SPECTRA OF NITROBENZENE-DO, NITROBENZENE-P-D AND NITROBENZENE-D5 AND NORMAL VIBRATIONS OF NITROBENZENE

被引:71
作者
KUWAE, A
MACHIDA, K
机构
[1] Faculty of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto
关键词
D O I
10.1016/0584-8539(79)80060-4
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Infrared and Raman spectra of nitrobenzene-p-d and -d5 have been recorded in the liquid state and sixty-seven of the seventy-two fundamental frequencies of the two isotopes have been assigned by referring to the isotopic frequency shifts, the Raman depolarization ratios and the assignments of sodium benzoate-p-d and -d5. A normal coordinate analysis has been carried out for the five isotopic nitrobenzenes, -d0, -p-d, -d5, -18O2 and -15N. The force constants have been refined by the method of least squares and a good fit between the observed and the calculated frequencies has been obtained. © 1979.
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页码:27 / 33
页数:7
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