SYNTHESIS OF THE GUAIANE (+/-)-ALISMOL USING A FREE-RADICAL FRAGMENTATION/ELIMINATION SEQUENCE

被引：35

作者：

LANGE, GL

GOTTARDO, C

机构：

[1] Guelph-Waterloo Centre for Graduate Work in Chemistry Department of Chemistry, Biochemistry University of Guelph, Guelph

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 46期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4039(00)78424-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of the guaiane alismol (3) is reported. The efficient, stereoselective and regioselective approach involves only eight steps, with the key transformation being a radical fragmentation/elimination sequence-which proceeds in high yield (92%).

引用

页码：8513 / 8516

页数：4

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