PROTON AFFINITY, IONIZATION-ENERGY, AND THE NATURE OF FRONTIER ORBITAL ELECTRON-DENSITY

被引：39

作者：

DEKOCK, RL

BARBACHYN, MR

机构：

[1] Contribution from the Department of Chemistry, Calvin College, Grand Rapids, Michigan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 22期

关键词：

D O I：

10.1021/ja00516a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study of the correlation between proton affinity and lowest ionization energy reveals that molecular bases fit into three broad categories: two-electron lone-pair bases, π or σ bond-pair bases, and one-electron bases with relatively high electronic rearrangement energies. A fourth group of bases that cannot be categorized consists of one-electron bases with relatively low electronic rearrangement energies. © 1979, American Chemical Society. All rights reserved.

引用

页码：6516 / 6519

页数：4

共 41 条

[21]

Herzberg G., 1950, ELECT SPECTRA ELECT

[22]

HUHEEY J, 1978, INORG CHEM, P602

[23] PHOTOELECTRON SPECTROSCOPY OF TRANSIENT SPECIES - CS MOLECULE [J].