SPECIFIC-HEAT, MAGNETIC-PROPERTIES AND CRITICAL-BEHAVIOR OF MN2SIS4 AND FE2GES4

被引：23

作者：

JUNOD, A ^{[1
]}

WANG, KQ ^{[1
]}

TRISCONE, G ^{[1
]}

LAMARCHE, G ^{[1
]}

机构：

[1] OTTAWA CARLETON INST PHYS,DEPT PHYS,OTTAWA,ON,CANADA

来源：

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 1995年 / 146卷 / 1-2期

关键词：

D O I：

10.1016/0304-8853(94)01665-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The olivine Mn2SiS4 is antiferromagnetic (AF) up to 83 K, behaves as a weak ferromagnet (WF) from 83 to 86 K, and becomes paramagnetic (P) at higher temperatures. Its counterpart Fe2GeS4 undergoes similar transitions in a reversed order: WF up to 69 K, AF up to 144 K and then P. These transitions are characterized by susceptibility measurements and investigated by high resolution specific heat experiments. The transition to the paramagnetic state is of the critical type and belongs to the universality class of the Heisenberg model for Mn2SiS4 and the 3D Ising model for Fe2GeS4. The WF/AF or AF/WF transition is of first order with a latent heat Delta H = 0.09 J/mol for Mn2SiS4 and Delta H = 105 J/mol for Fe2GeS4. The lattice is found to be stiffer for the Mn thiosilicate than for the Fe thiogermanate.

引用

页码：21 / 29

页数：9

共 16 条

[1] NEUTRON DIFFRACTION STUDY OF NUCLEAR AND MAGNETIC STRUCTURE OF MANGANESE ORTHOTHIOGERMANATE [J].