NEW INTERCALATION COMPOUNDS OF C-60 WITH CESIUM

被引：16

作者：

MESSAOUDI, A

CONARD, J

SETTON, R

BEGUIN, F

机构：

[1] CRMD, CNRS-Université d' Orléans, 45071 Orleans Cedex 02, 1B, rue de la Férollerie

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 202卷 / 06期

关键词：

D O I：

10.1016/0009-2614(93)90039-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the preparation Of CS3C60 by direct reaction of Cs vapor on C60. As against K3C60 and Rb3C60 which are both face centered cubic (fcc), CS3C60 is body-centered cubic (bcc). Cs1C60 was also prepared and found to be fcc, but we did not observe any phase separation, as reported by Tycko et al. for K(x)C60 (0<x< 3). This is the first evidence that the octahedral sites of the C60 lattice can be preferentially filled by alkali metal atoms.

引用

页码：506 / 508

页数：3

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