AN ALKYLPEROXOIRON(III) INTERMEDIATE AND ITS ROLE IN THE OXIDATION OF ALIPHATIC C-H BONDS

被引：93

作者：

KIM, J ^{[1
]}

LARKA, E ^{[1
]}

WILKINSON, EC ^{[1
]}

QUE, L ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 18期

关键词：

C-H ACTIVATION; IRON COMPOUNDS; MASS SPECTROMETRY; PEROXO COMPLEXES;

D O I：

10.1002/anie.199520481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3. tpa = tris(2‐pyridylmethyl)amine. (Formula Presented.) (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2048 / 2051

页数：4

共 20 条

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