ON THE MECHANISM OF TITANOCENEDICHLORIDE-CATALYZED HYDROMAGNESIATION OF ALKYNES WITH ALKYL GRIGNARD-REAGENTS

被引：41

作者：

GAO, Y ^{[1
]}

SATO, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOMOLEC ENGN,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000659

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of titanocenedichloride-catalysed hydromagnesiation reaction of alkynes with an alkyl Grignard reagent is elucidated and it is revealed that the regiochemistry of the, reaction controlled at the step of transmetallation from titanium to magnesium.

引用

页码：659 / 660

页数：2

共 32 条

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